Elucidating the Reaction Mechanism of Mn<sup>2+</sup> Electrolyte Additives in Aqueous Zinc Batteries (Small 38/2023)
نویسندگان
چکیده
Aqueous Zinc Batteries In article number 2301770, Yueliang Gu, Xiaochuan Ren, Daming Zhu, Jianxin Zou, and co-workers elucidate the reaction mechanism of Mn2+ electrolyte additives in aqueous zinc batteries (ZIBs) via operando synchrotron X-ray diffraction, ex situ absorption spectroscopy electrochemical analyses. A reversible Mn2+/MnO2 deposition/dissolution occurred at cathode, which change environment enabled Zn2+/Zn4SO4(OH)6•5H2O deposition/dissolution. The chemical contributes no capacity hinders diffusion kinetics reaction, prevents operation ZIBs high currents.
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ژورنال
عنوان ژورنال: Small
سال: 2023
ISSN: ['1613-6829', '1613-6810']
DOI: https://doi.org/10.1002/smll.202370311